1,4-Phenylene diisocyanate Bulk Supply for Industrial Use

China Factory Direct
CAS number 104-49-4
Product name 1,4-Phenylene diisocyanate
Stock Stock readily available; annual supply capacity exceeding 1,000 tons.
Grade Material GradeSpecialty GradeIndustrial Grade
Packaging 25KG/bag500KG/bag1000KG/bag
Sample Test Samples Available (Click to Request Samples)
COA View COA
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Supply Type Bulk / Contract manufacturing / OEM
Shipping FCL / LCL available
Payment Terms Support FOB \ CIF \ EXW quotations, and accept Letter of Credit (L/C).
Manufacturer Greenrock Chemical(China Factory)
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CAS No:104-49-4
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Documents We Provide for 1,4-Phenylene diisocyanate

COA TDS SDS NMR MOA Certificate of Origin Transport Report TSCA Declaration Production Flow Chart
Pre-sale: Only COA, SDS and NMR are available.
Post-sale: Full documentation is provided.
To request documents, please contact us via email at sales@GRchemical.com.
Bulk 1,4-Phenylene diisocyanate Supplier from China

17+ years in chemical exports.Fully compliant, reliable supply.Your B2B partner in bulk chemical procurement.

Industrial Applications of 1,4-Phenylene diisocyanate

Industry Application Process
Polyurethane Production of polyurethane foam Reacted directly with polyols to produce polyurethane
Coatings Formulation of coatings and adhesives Used in copolymerization or as a crosslinking agent
Elastomers Production of elastomeric materials Reacted with polyether or polyester polyols
Fibers Production of specialty fibers Reacted with specific polymers to prepare fiber precursors

Manufacturing Quality Control of 1,4-Phenylene diisocyanate

Detection Item Common Analytical Method Method Overview
Assay (Purity) Gas Chromatography (GC) with FID detection Quantifies TDI isomers by separation on a capillary column and flame ionization detection relative to internal standard.
Isomer Ratio (2,4-TDI / 2,6-TDI) Gas Chromatography (GC) with FID detection Determines relative peak areas of 2,4- and 2,6-isomers after chromatographic separation.
Color (APHA) Visual comparison or spectrophotometric measurement at 430 nm Measures yellowness intensity by comparing sample absorbance at 430 nm to APHA color scale standards.
Water Content Karl Fischer Titration (coulometric or volumetric) Electrochemical titration quantifying water via iodine generation and stoichiometric reaction with water.
Acidity (as HCl) Acid-Base Titration with NaOH and potentiometric endpoint Neutralizes acidic impurities (e.g., HCl) using standardized sodium hydroxide solution; endpoint detected by pH change.
Iron Content ICP-OES Atomizes sample in plasma and measures characteristic emission intensity of Fe at 238.204 nm.
Chloride Ion Content Ion Chromatography (IC) with conductivity detection Separates and quantifies Cl- anions using anion-exchange column and suppressed conductivity detection.
Residue on Evaporation Gravimetric Analysis Evaporates known volume under controlled conditions and weighs non-volatile residue.
Density at 25 C Digital Density Meter (oscillating U-tube principle) Measures density based on resonant frequency shift of a vibrating U-shaped tube filled with sample.
Refractive Index at 25 C Abbe Refractometer Determines refractive index by measuring critical angle of total internal reflection.
Free Isocyanate Content Back Titration with dibutylamine and HCl Reacts NCO groups with excess dibutylamine, then titrates unreacted amine with standardized HCl.
Heavy Metals (as Pb) AAS (Flame or Graphite Furnace) Atomizes sample and measures absorbance of lead-specific wavelength (283.3 nm) after air-acetylene or graphite furnace atomization.

Technical Specifications of 1,4-Phenylene diisocyanate

Test Item Specification
Appearance White to light yellow crystalline powder
Purity >=98.0% (GC-MS)
Water Content (KF) <=0.5%
Total Impurities <=2.0%
Single Impurity <=0.5%
Melting Point 130–134°C
Identification (IR) Conforms to reference spectrum
Color (APHA/Pt-Co) <=100
Specifications vary by industry. Reach out to our technical experts for a COA tailored specifically to your application. Email:selse@GRchemical.com

Download COA of 1,4-Phenylene diisocyanate

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NMR Spectra of 1,4-Phenylene diisocyanate

Safety Information of 1,4-Phenylene diisocyanate

Pictograms
Signal Word Danger
Safety Data Sheet

Packaging of 1,4-Phenylene diisocyanate

We have a diverse range of chemicals in stock. Available in Bagged goods (25 kg.),Big bags (500 kg.), Big bags (1000 kg.).

Industrial 1,4-Phenylene diisocyanate Procurement FAQ

1. How do you ensure product quality consistency?
We rely on a mature China-based manufacturing system and implement strict batch control and quality inspection for every shipment. Our production process complies with ISO 9001 standards, and a COA is provided for each batch to ensure consistent and reliable quality.

2. Do you offer competitive pricing for bulk orders?
Yes, as a China-based manufacturer and bulk supplier, we provide tiered pricing based on order volume. We support FOB and CIF quotations, as well as L/C payment terms for large transactions to meet international trade requirements.

3. Can you support large-volume or long-term supply?
We have stable production capacity and a well-established supply chain, enabling continuous bulk supply. We support ton-level and container-level orders, as well as long-term cooperation projects.

4. What is your typical lead time?
For in-stock products, shipment can be arranged within 1–3 days. For bulk packaging or customized orders, lead time depends on the specific quantity and production schedule.

5. What documents do you provide?
We can provide complete documentation upon request, including COA, SDS, TDS, and other compliance certificates, meeting industrial procurement and export requirements.

6. Can you customize product specifications or packaging?
Yes, we support customization of parameters such as purity, impurities, residual solvents, and heavy metals. We also offer various bulk packaging options, including 25kg bags, drums, and IBC tanks, suitable for industrial applications and transportation.

7. What shipping options do you support?
We support both FCL (Full Container Load) and LCL (Less than Container Load) shipments, and can flexibly arrange logistics solutions based on order size to meet bulk chemical export needs.

8. Do you provide technical or application support?
Yes, we provide basic application guidance and technical support based on industry experience to help customers optimize product usage.

9. How do you handle compliance and export regulations?
We are familiar with international trade and export regulations, ensuring all products comply with relevant requirements. We also provide complete documentation to support smooth customs clearance and global delivery.

Industrial
Use
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Factory
Direct
ISO 9001
Certified
Samples
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Stable
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