China Factory Direct
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| CAS number | 25035-69-2 |
| Product name | Methacrylic acid, polymer with butyl acrylate and methyl methacrylate |
| Stock | Stock readily available; annual supply capacity exceeding 1,000 tons. |
| Grade | Material GradeSpecialty GradeIndustrial GradeCosmetic GradeFood Grade |
| Packaging | 25KG/bag500KG/bag1000KG/bag |
| Sample | Test Samples Available (Click to Request Samples) |
| COA | View COA |
| Price | Get Quote |
| Supply Type | Bulk / Contract manufacturing / OEM |
| Shipping | FCL / LCL available |
| Payment Terms | Support FOB \ CIF \ EXW quotations, and accept Letter of Credit (L/C). |
| Manufacturer | Greenrock Chemical(China Factory) |
Based on current marketvolatility and material availability.
17+ years in chemical exports.Fully compliant, reliable supply.Your B2B partner in bulk chemical procurement.
| Industry | Application | Process |
|---|---|---|
| Coatings | Provides excellent weather resistance and adhesion; serves as a film-forming agent | Acrylic (ester) copolymers are prepared via emulsion or solution polymerization, then blended with other components to formulate coating systems |
| Textile Treatment | Improves fabric hand feel, wrinkle resistance, and dyeability | Acrylic (ester) copolymers are applied as finishing agents onto textile surfaces using an impregnation-drying process |
| Construction | Serves as a base component in waterproofing agents, sealants, and other construction materials | Products with targeted performance are synthesized via controlled copolymerization under specific conditions, then processed into final forms such as liquids or pastes |
| Papermaking | Enhances paper strength, wet strength, and printability | Acrylic (ester) copolymers are added to the pulp slurry or applied via coating during later stages of paper production |
| Personal Care | Functions as a thickener, stabilizer, and similar additive in cosmetics and personal care products | Copolymerization is carried out with selected monomers, and molecular weight is adjusted to meet requirements of specific applications |
| Water Treatment | Acts as a flocculant to remove suspended solids from water | Copolymer charge characteristics and molecular structure are tailored to optimize performance in water treatment processes |
| Test Item | Common Test Method | Method Overview |
|---|---|---|
| Solid Content | Oven Drying Method (GB/T 1725) | The sample is dried to constant weight at a specified temperature (e.g., 105±2°C), and the solid content is calculated based on mass loss. Suitable for aqueous or solvent-based acrylic copolymer emulsions or solutions. |
| Average Molecular Weight and Molecular Weight Distribution | Gel Permeation Chromatography (GPC/SEC) | The sample is dissolved in an organic solvent (e.g., THF), separated by molecular weight through a chromatographic column, and analyzed using a calibration curve to determine number-average molecular weight (Mn), weight-average molecular weight (Mw), and polydispersity index (PDI). |
| Residual Acrylic Monomer | Gas Chromatography (GC) or High-Performance Liquid Chromatography (HPLC) | After appropriate pretreatment (e.g., extraction, dilution), residual unreacted acrylic or acrylate monomers are quantified using GC or HPLC to ensure compliance with safety standards (e.g., cosmetic regulations). |
| Acid Value (Saponification Value) | Titration Method (GB/T 6365) | The carboxylic acid groups in the sample are titrated with a standard alkaline solution (e.g., NaOH). The result is expressed as milligrams of KOH consumed per gram of sample, indicating the content of acidic groups, which affects pH and stability. |
| pH Value | pH Meter Method | The sample is prepared as an aqueous solution at a specified concentration and measured directly using a calibrated pH meter. Essential for assessing acidity/basicity and ensuring stability in applications such as cosmetics and coatings. |
| Viscosity | Rotational Viscometer Method (e.g., Brookfield) | Measures the resistance of the sample under a rotating spindle at a set speed and temperature, yielding dynamic viscosity in mPa·s. Used to control application properties and rheological behavior. |
| Transmittance / Turbidity | UV-Visible Spectrophotometry (UV-Vis) | The diluted sample is measured at a specific wavelength (e.g., 550 nm) to determine transmittance, evaluating the clarity of the polymer solution and reflecting emulsion stability or impurity levels. |
| Particle Size Distribution (for Emulsions) | Dynamic Light Scattering (DLS) | Laser light is directed at the emulsion particles; fluctuations in scattered light intensity are analyzed to calculate particle size distribution (Z-average diameter, PDI), used to assess emulsion stability and film-forming properties. |
| Thermal Stability | Thermogravimetric Analysis (TGA) | Measures sample mass change under programmed temperature conditions (e.g., 25–600°C) to analyze decomposition temperature and residue (char) content, evaluating the polymer’s heat resistance. |
| Heavy Metal Content | Atomic Absorption Spectroscopy (AAS) or Inductively Coupled Plasma Mass Spectrometry (ICP-MS) | After digestion, the sample is analyzed by AAS or ICP-MS to determine concentrations of heavy metals (e.g., Pb, Cd, Hg, As), ensuring compliance with regulatory requirements for cosmetics, food-contact materials (e.g., EU Regulation EC 1223/2009). |
| Total Free Monomers | LC-MS/MS (Liquid Chromatography-Tandem Mass Spectrometry) | High-sensitivity detection of trace unreacted monomers (e.g., methyl methacrylate, butyl acrylate), suitable for high-purity applications such as medical polymers or food packaging materials. |
| Saponification Value | Alkaline Hydrolysis-Titration Method | Ester groups are hydrolyzed under basic conditions, excess base is back-titrated with acid, and the KOH consumed per gram of sample is calculated. Reflects ester group content and helps control hydrophilic/lipophilic balance in copolymers. |
| Water Solubility / Dispersion Stability | Centrifugation or Standing Observation Method | The sample is centrifuged (e.g., 3000 rpm, 30 min) or left standing to observe phase separation or precipitation, evaluating its dispersion stability in water—important for water-based coatings and personal care formulations. |
| Infrared Spectroscopy (Structural Confirmation) | Fourier Transform Infrared Spectroscopy (FTIR) | Characteristic absorption peaks (e.g., C=O at 1730 cm⁻¹, C-O at 1150–1250 cm⁻¹) confirm the presence of acrylic ester structures, identifying target functional groups or potential contaminants. |
| Residual Solvents | Headspace Gas Chromatography (HS-GC) | For solvent-based products, headspace sampling is used to detect residual solvents such as ethanol, acetone, or toluene, ensuring compliance with standards like ICH Q3C or GB 31604.8. |
| Test Item | Specification |
|---|---|
| Appearance | Colorless to pale yellow viscous liquid |
| Purity | >=98.5% |
| Water Content (KF) | <=0.5% |
| Acid Value (mg KOH/g) | 120-180 |
| Color (APHA/Pt-Co) | <=100 |
| Odor | Characteristic acrid odor |
| Solubility | Miscible with water and common organic solvents |
| Total Impurities | <=1.5% |
| Single Impurity | <=0.5% |
| Heavy Metals | <=20 ppm |
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| CAS/Product ID | *Required fields | |
| Lot/Batch Number | *Required fields | |
1. How do you ensure product quality consistency?
We rely on a mature China-based manufacturing system and implement strict batch control and quality inspection for every shipment. Our production process complies with ISO 9001 standards, and a COA is provided for each batch to ensure consistent and reliable quality.
2. Do you offer competitive pricing for bulk orders?
Yes, as a China-based manufacturer and bulk supplier, we provide tiered pricing based on order volume. We support FOB and CIF quotations, as well as L/C payment terms for large transactions to meet international trade requirements.
3. Can you support large-volume or long-term supply?
We have stable production capacity and a well-established supply chain, enabling continuous bulk supply. We support ton-level and container-level orders, as well as long-term cooperation projects.
4. What is your typical lead time?
For in-stock products, shipment can be arranged within 1–3 days. For bulk packaging or customized orders, lead time depends on the specific quantity and production schedule.
5. What documents do you provide?
We can provide complete documentation upon request, including COA, SDS, TDS, and other compliance certificates, meeting industrial procurement and export requirements.
6. Can you customize product specifications or packaging?
Yes, we support customization of parameters such as purity, impurities, residual solvents, and heavy metals. We also offer various bulk packaging options, including 25kg bags, drums, and IBC tanks, suitable for industrial applications and transportation.
7. What shipping options do you support?
We support both FCL (Full Container Load) and LCL (Less than Container Load) shipments, and can flexibly arrange logistics solutions based on order size to meet bulk chemical export needs.
8. Do you provide technical or application support?
Yes, we provide basic application guidance and technical support based on industry experience to help customers optimize product usage.
9. How do you handle compliance and export regulations?
We are familiar with international trade and export regulations, ensuring all products comply with relevant requirements. We also provide complete documentation to support smooth customs clearance and global delivery.